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51.
The enrichment of boron relative to similarly incompatible elements,such as Be, in arc volcanic rocks has been used as a proxy forthe involvement of slab flux in petrogenesis. New ion microprobeanalyses of single glass shards in tephra layers recovered bythe Ocean Drilling Program (ODP) in the Izu and NE Japan forearcbasins now allow the temporal variation in slab flux to be chartedsince 7 and 5 Ma, respectively. B/Be ratios are typically <70in NE Japan and <130 in Izu, with no single grain exceeding200. Although moderate to high for modern arcs, these valuesare much less than those recorded in the Marianas and Tongaat 3–4 Ma, shortly after the start of rifting of theirback-arc basins. This observation suggests that the peak B/Bevalues seen in Tonga and the Marianas are related to the tectonicsof slab roll-back and basin opening, rather than changes inthe dynamics of the Pacific Plate. There is no temporal trendto enrichment in the high field strength elements (HFSE) orrare earth elements (REE) in either Izu or NE Japan since 7Ma, although the two elemental groups do show clear positivecorrelation. A lack of correlation between REE, HFSE and B/Besuggests that slab flux is not the only control on melting inthese arcs.  相似文献   
52.
Anatectic veins containing the Be minerals khmaralite and berylliansapphirine as primary phases (or surinamite derived therefrom)are associated with Mg–Al-rich paragneisses at three localitiesin the ultrahigh-temperature Napier complex, Antarctica, a uniqueBe mineralization in the granulite facies. Likely precursorsof the paragneisses are volcaniclastic deposits that were hydrothermallyaltered by heated seawater prior to metamorphism. Regular distributionof Be among minerals in the paragneisses suggests an approachto equilibrium with Be greatly concentrated in sapphirine (25–3430ppm Be) or cordierite (560–930 ppm Be) relative to plagioclaseAn53–66 (14–43 ppm Be) > cores of coarse-grainedorthopyroxene (0·7–29 ppm Be) > coronitic orthopyroxene(0·4–14 ppm Be) sillimanite (0·1–26ppm Be) plagioclase An18–33 (0·6–15 ppmBe) > biotite (0·06–8 ppm Be) > K-feldspar,quartz, garnet (0·05–0·7 ppm Be). Sapphirine-bearingparagneisses have average Be concentrations, 4·9 ±2·4 ppm (13 samples), about twice that of typical pelites,whereas paragneisses lacking sapphirine and primary cordieritehave only 2·9 ± 2·1 ppm Be (12 samples),implying some loss of Be during metamorphism. The likely sourcerocks for the Be-rich melts were biotitic rocks lacking theBe sinks sapphirine and cordierite. These gneisses were probablyless competent than the sapphirine-bearing gneisses, so themelts were drawn to the latter and collected in spaces openedduring deformation and boudinage of the more competent paragneisses.Fractionation of the melts concentrated Be to the extent thatBe minerals could crystallize. The final result was Be-mineralizedanatectic veins hosted by relatively Be-rich sapphirine-bearingparagneisses. KEY WORDS: Antarctica; beryllium; granulite facies; microprobe; sapphirine  相似文献   
53.
Jurassic age volcanic rocks of the Stonyford volcanic complex(SFVC) comprise three distinct petrological groups based ontheir whole-rock geochemistry: (1) oceanic tholeiites; (2) transitionalalkali basalts and glasses; (3) high-Al, low-Ti tholeiites.Major and trace element, and Sr–Nd–Pb isotopic dataindicate that the oceanic tholeiites formed as low-degree partialmelts of normal mid-ocean ridge basalt (N-MORB)-source asthenospheresimilar in isotope composition to the East Pacific Rise today;the alkalic lavas were derived from an enriched source similarto that of E-MORB. The high-Al, low-Ti lavas resemble second-stagemelts of a depleted MORB-source asthenosphere that formed bymelting spinel lherzolite at low pressures. Trace element systematicsof the high-Al, low-Ti basalts show the influence of an enrichedcomponent, which overprints generally depleted trace elementcharacteristics. Tectonic discrimination diagrams show thatthe oceanic tholeiite and alkali suites are similar to present-daybasalts generated at mid-oceanic ridges. The high-Al, low-Tisuite resembles primitive arc basalts with an enriched, alkalibasalt-like overprint. Isotopic data show the influence of recycledcomponents in all three suites. The SFVC was constructed ona substrate of normal Coast Range ophiolite in an extensionalforearc setting. The close juxtaposition of the MORB-like olivinetholeiites with alkali and high-Al, low-Ti basalts suggestsderivation from a hybrid mantle source region that includedMORB-source asthenosphere, enriched oceanic asthenosphere, andthe depleted supra-subduction zone mantle wedge. We proposethat the SFVC formed in response to collision of a mid-oceanridge spreading center with the Coast Range ophiolite subductionzone. Formation of a slab window beneath the forearc duringcollision allowed the influx of ridge-derived magmas or themantle source of these magmas. Continued melting of the previouslydepleted mantle wedge above the now defunct subduction zoneproduced strongly depleted high-Al, low-Ti basalts that werepartially fertilized with enriched, alkali basalt-type meltsand slab-derived fluids. KEY WORDS: CRO; oceanic basalts; California  相似文献   
54.
The simultaneous eruption in 1996 of andesite from Karymskyvolcano and of basalt from the Academy Nauk vent 6 km away appearsto provide a case of mafic recharge of an andesite reservoirfor which the time of recharge is exactly known and direct samplesof the recharging magma are available. The explosive phreato-magmaticeruption of basalt was terminated in less than 24 h, whereasandesite erupted continuously during the following 4 years.Detailed petrological study of volcanic ash, bombs and lavasof Karymsky andesite erupted during the period 1996–1999provides evidence for basaltic replenishment at the beginningof the eruptive cycle, as well as a record of compositionalvariations within the Karymsky magma reservoir induced by basalticrecharge. Shortly after the beginning of the eruption the compositionof the matrix glass of the Karymsky tephra became more maficand then, within 2 months, gradually returned to its originalstate and remained almost constant for the following 3 years.Further evidence for basaltic replenishment is provided by thepresence of xenocrysts of basaltic origin in the andesite ofKarymsky. A conspicuous portion of the plagioclase phenocrystsin the Karymsky andesite has calcic cores, with compositionsand textures resembling those of plagioclases in the AcademyNauk basalt. Similarly, the earlier portion of the andesiteof the eruption sequence contains rare olivines, which occuras resorbed cores in pyroxenes. The composition of the olivinematches that of olivines in the Academy Nauk basalt. The sequenceof events appears to be: (1) injection of basaltic magma intothe Karymsky chamber with immediate, compensating expulsionof pre-existing chamber magma from the Karymsky central vent;(2) direct mixing of basaltic and andesitic magmas with dispersalof phenocrysts associated with the basalt throughout the andesiteso that newly mixed magma appeared at the vent within 2 months;(3) re-establishment of thermal and chemical equilibrium withinthe reservoir involving crystallization in the new hybrid liquid,which returned the melt composition to ‘normal’,formed rims on inherited calcic plagioclase, and caused theresorption of dispersed olivine xenocrysts. Taken together,these findings indicate that the Karymsky magma reservoir wasrecharged by basalt at the onset of the 1996 eruptive cycle.The rapidity and thoroughness of mixing of the basalt with thepre-existing andesite probably reflects the modest contrastin temperature, viscosity, and density between the two magmas. KEY WORDS: Karymsky; Kamchatka; magma mixing; andesite; volcanic glass; plagioclase  相似文献   
55.
Experimental petrologists have successfully located basalticliquid compositions parental to mid-ocean ridge basalt thatare, within experimental resolution, multiply saturated withthree-phase harzburgite or four-phase lherzolite assemblageson their liquidus at some elevated pressure. Such an experimentalresult is a necessary consequence of any paradigm in which eruptedbasalts derive from single-batch primary liquids that equilibratewith a mantle residue and undergo no subsequent magma mixingbefore differentiation and eruption. Here we investigate whether,conversely, such evidence of multiple saturation is sufficientto exclude dynamic melting models wherein increments of meltare mixed after segregation from residues, during melt transportor in magma chambers. Using two independent models of crystal–liquidequilibria to simulate polybaric near-fractional peridotitemelting, we find that aggregate liquids from such melting processescan display near-intersections of liquidus surfaces too closeto distinguish experimentally from exact multiple saturationpoints. Given uncertainties in glass compositions, fractionationcorrections, experimental temperature and pressure conditions,and achievement of equilibrium, these results suggest that polybaricmixtures can in fact masquerade as mantle-equilibrated single-batchprimary liquids. Multiple saturation points on the liquidussurfaces of primitive basalts do, however, preserve informationabout the average pressure of extraction of their constituentincrements of liquid. KEY WORDS: mantle melting; basaltic volcanism; experimental igneous petrology; thermodynamic modelling; inverse method  相似文献   
56.
The fault-bounded Bolívar Ultramafic Complex (BUC) onthe eastern fringes of the Western Cordillera of Colombia wastectonically accreted onto the western coast of South Americain the late Cretaceous–early Tertiary, along with pillowbasalts of the Caribbean–Colombian Oceanic Plateau (CCOP).The complex consists of a lower sequence of ultramafic cumulates,successively overlain by layered and isotropic gabbroic rocks.The gabbros grade into, and are intruded by, mafic pegmatitesthat consist of large magnesiohornblende and plagioclase crystals.These pegmatites yield a weighted mean 40Ar–39Ar step-heatingage of 90·5 ± 0·9 Ma and thus coincidewith the timing of peak CCOP volcanism. The chemistry of theBUC is not consistent with a subduction-related origin. However,the similarity in Sr–Nd–Pb–Hf isotopes betweenthe CCOP and the BUC, in conjunction with their indistinguishableages, suggests that the BUC is an integral part of the plume-derivedCCOP. The parental magmas of the Bolívar complex wereprobably hydrous picrites that underwent 20–30% crystallization.The residual magmas from this fractionation contained  相似文献   
57.
Dehydration melting experiments of alkali basalt associatedwith the Kenya Rift were performed at 0·7 and 1·0GPa, 850–1100°C, 3–5 wt % H2O, and fO2 nearnickel–nickel oxide. Carbon dioxide [XCO2 = molar CO2/(H2O+ CO2) = 0·2–0·9] was added to experimentsat 1025 and 1050°C. Dehydration melting in the system alkalibasalt–H2O produces quartz- and corundum-normative trachyandesite(6–7·5 wt % total alkalis) at 1000 and 1025°Cby the incongruent melting of amphibole (pargasite–magnesiohastingsite).Dehydration melting in the system alkali basalt–H2O–CO2produces nepheline-normative tephriphonolite, trachyandesite,and trachyte (10·5–12 wt % total alkalis). In thelatter case, the solidus is raised relative to the hydrous system,less melt is produced, and the incongruent melting reactioninvolves kaersutite. The role of carbon dioxide in alkalinemagma genesis is well documented for mantle systems. This studyshows that carbon dioxide is also important to the petrogenesisof alkaline magmas at the lower pressures of crustal systems.Select suites of continental alkaline rocks, including thosecontaining phonolite, may be derived by low-pressure dehydrationmelting of an alkali basalt–carbon dioxide crustal system. KEY WORDS: alkali basalt; alkaline rocks; carbon dioxide; dehydration melting; phonolite  相似文献   
58.
The Chippewa and Wisconsin Valley Lobes of the Laurentide Ice Sheet reached their maximum extent in north-central Wisconsin about 20 000 years ago. Their terminal positions are marked by a broad area of hummocky topography, containing many ice-walled-lake plains, which is bounded on the up-ice and down-ice sides by ice-contact ridges and outwash fans. The distribution of these ice-disintegration landforms shows that a wide zone of stagnant, debris-covered, debris-rich ice separated from the active margins of both lobes as they wasted northward during deglaciation. Accumulation of thick, uncollapsed sediment in ice-walled lakes high in the ice-cored landscape indicates a period of stability. In contrast, hummocky disintegration topography indicates unstable conditions. Thus, we interpret two phases of late-glacial landscape evolution. During the first phase, ice buried beneath thick supraglacial sediment was stable. Supraglacial lakes formed on the ice surface and some melted their way to solid ground and formed ice-walled lakes. During the second phase, buried ice began to melt rapidly, hummocky topography formed by topographic inversion, and supraglacial and ice-walled lakes drained. We suggest that ice wastage was controlled primarily by climatic conditions and supraglacial-debris thickness. Late-glacial permafrost in northern Wisconsin likely delayed wastage of buried ice until after about 13 000 years ago, when climate warmed and permafrost thawed.  相似文献   
59.
The retreat of the Barents Sea Ice Sheet on the western Svalbard margin   总被引:1,自引:0,他引:1  
The deglaciation of the continental shelf to the west of Spitsbergen and the main fjord, Isfjorden. is discussed based on sub-bottom seismic records and scdirncnt cores. The sea lloor on the shelf to the west of Isfjorden is underlain by less than 2 m of glaciomarine sediments over a firm diamicton interpreted as till. In central Isfjordcn up to 10 m of deglaciation sediments were recorded, whereas in cores from the innermost tributary, Billefjorden, less than a meter of ice proximal sediments was recognized between the till and the 'normal' Holocene marine sediments. We conclude that the Barents Sea Ice Sheet terminated along the shelf break during the Late Weichselian glacial maximum. Radiocarbon dates from thc glaciomarine sediments above the till indicate a stepwise deglaciation. Apparently the ice front rctrcatcd from the outermost shelf around 14. 8 ka A dramatic increase in the flux of line-grained glaciomarine sediments around 13 ka is assumed to reflect increased melting and/or current activity due to a climatic warming. This second stage of deglaciation was intcrruptcd by a glacial readvance culminating on the mid-shelf area shortly after 12.4 ka. The glacial readvance, which is correlated with a simultaneous readvance of the Fennoscundian ice sheet along the western coast of Norway, is attributed to the so-called 'Older Dryas' cooling event in the North Atlantic region. Following this glacial readvance the outer part of Isljorden became rapidly deglaciated around 12.3 ka. During the Younger Dryas the inner fjord branches were occupied by large outlet glaciers and possibly the ice liont terminated far out in the main fjord. The remnants of the Harcnts Sea Ice Shcet melted quickly away as a response to the Holocene warming around 10 ka.  相似文献   
60.
The spinel lherzolite massif at Balmuccia, northwest Italy,forms an elongate north-south trending lens (4.5 x 0.5 x 1.1km) within the pre-Alpine granulite basement complex of theIvrea zone. The western contact is a mylonite fault zone formedduring late emplacement cataclastic flow near the Insubric line;to the east the lherzolite massif is separated from the granulitesby a magmatic sheath of layered pyroxenites, pyroxene pegmatitesand meta-gabbros. Pyroxene reaction zones on gabbro dikes indunite pods which lie east of the main lherzolite massif showthat emplacement occurred at pressures >9 kb, based on peridotiteequilibria studies. Phase chemistry calculations on pyroxenitesand granulites show ambient P–T conditions to have been850 °C (Cpx–Opx equilibria) and 10–13 kb (Opx–Gt;Plg–Gt–Sill–Qtz) during emplacement of thelherzolite massif. Temperature calculations on 12 peridotitesfrom throughout the massif suggest an earlier high-T stage (1200°C; Ol–Px–Sp) followed by partial re-equilibrationat lower T (850–950 °C; Cpx–Opx). The areaswithin the lherzolite massif with the highest calculated Ol–Px–Sptemperatures have the lowest Cpx–Opx temperatures, suggestingthat the apparent Cpx–Opx temperatures are due to re-equilibrationduring emplacement. The spinel lherzolite probably originatedat 12 and 20 kb, based on the mineral assemblage Ol + Opx +Cpx + Sp + Hnbd. The inferred P–T ranges put both themassif and the granulites on a geotherm that is high for continentalcrust and implies a high surface heat flow at the time of emplacement(2.2 µcal/cm2 sec). The Balmuccia area later became thelocus of early Mesozoic rifting between the North and SouthAlpine plates. These relationships at Balmuccia are similarto the Great Basin of the western United States, where mantlexenoliths in young basalts that show P–T conditions of1100–1300 °C at 17–20 kb, occur in an area ofhigh heat flow (2.0 µCal/cm2 sec average) and extension.This suggests an association between up-welling of mantle peridotitesbelow continents and ensialic tensional tectonics.  相似文献   
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